Germany's Henseleit and Ireland's Leona Maguire will play Andrea Lee and debutant Lindy Duncan, while Swedish duo Maja Stark and Linn Grant get started against Rose Zhang and Jennifer Kupcho.
The United States have dominated the previous two opening foursomes sessions, winning 4-0 at Finca Cortesin in 2023 and taking a 3-1 advantage at the Robert Trent Jones Golf Club in 2024.
Europe are looking to regain the trophy after losing 15½-12½ in Virginia two years ago in the biggest team competition in women's golf.
